C -Methylcalix[4]resorcinarene–1,4-bis(pyridin-3-yl)-2,3-diaza-1,3-butadiene (1/2)

  1. Get@NRC: C -Methylcalix[4]resorcinarene–1,4-bis(pyridin-3-yl)-2,3-diaza-1,3-butadiene (1/2) (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1107/S1600536811054717
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AbstractIn the title compound, 2C12H10N4·C32H32O8, the calixarene adopts a rctt conformation with dihedral angles of 138.40 (1) and 9.10 (1)° between the opposite rings. The dihedral angles between the rings of the pyridine derivative are 8.80 (1) and 9.20 (1)°. In the crystal, adjacent C-methylcalix[4]resorcinarene molecules are connected into columns parallel to [010] by O-H...O hydrogen bonds. O-H...N hydrogen bonds between the axial phenoxyl groups and bipyridine molecules link the columns into sheets parallel to (011), which are connected by O-H...N hydrogen bonds. Further O-H...N hydrogen bonds link the bipyridine and C-methylcalix[4]resorcinarene molecules, giving rise to a three-dimensional network.
AffiliationNRC Steacie Institute for Molecular Sciences; National Research Council Canada
Peer reviewedYes
NPARC number21269066
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Record identifierfa8557f4-d286-4105-9611-76dc225c7946
Record created2013-12-04
Record modified2016-05-09
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