TY  - JOUR
ID  - 20951807
AU  - Grinberg, Patricia
AU  - Sturgeon, Ralph E.
AU  - Gardner, Graeme
T1  - Identification of volatile iron species generated by UV photolysis
JO  - Microchemical Journal
PB  - Elsevier
SP  - 44
EP  - 47
VL  - 105
PY  - 2012
KW  - volatile metal species; vapor generation; iron; iron pentacarbonyl; GC-MS; silylation
N2  - The volatile products of photochemical generation (PVG) of iron from solutions of formic and acetic acids were examined by GC-MS. Iron pentacarbonyl was the sole analytical species detected in both cases, as confirmed by comparison of the results with a NIST reference spectrum. Silylation of the interior surfaces of the quartz tubing comprising the photochemical reactor essentially eliminated memory effects such that signal duration was determined simply by the residence time of the sample solution.
M1  - MICROC 1591
DO  - http://dx.doi.org/10.1016/j.microc.2012.05.036
U3  - Measurement Science and Standards
U3  - Science des mesures et étalons (SME-MSS)
U3  - National Research Council Canada
U3  - Conseil national de recherches Canada (CNRC-NRC)
SN  - 0026-265X
ER  -