Solid-state (73) Ge NMR spectroscopy of simple organogermanes

Hanson, Margaret A.; Sutrisno, Andre; Terskikh, Victor V.; Baines, Kim M.; Huang, Yining

doi:10.1002/chem.201201944

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DOI: Resolve DOI: http://dx.doi.org/10.1002/chem.201201944

Solid-state (73) Ge NMR spectroscopy of simple organogermanes

Author(s):

Search for Hanson, Margaret A.; Search for Sutrisno, Andre; Search for Terskikh, Victor V.; Search for Baines, Kim M.; Search for Huang, Yining

Affiliation:

Measurement Science and Standards; National Research Council Canada

Language:

English

Type:

Article

Journal:

Chemistry : a European Journal

Volume:

Issue:

Date:

2012

Pages :

13770-13779

NRCC #:

NPArC #:

20955687

Keywords:

density functional calculations; germanium; NMR spectroscopy

Abstract:

Germanium-73 is an extremely challenging nucleus to examine by NMR spectroscopy due to its unfavorable NMR properties. Through the use of an ultrahigh (21.1 T) magnetic field, a systematic study of a series of simple organogermanes was carried out. In those cases for which X-ray structural data were available, correlations were drawn between the NMR parameters and structural metrics. These data were combined with DFT calculations to obtain insight into the structures of several compounds with unknown crystal structures.

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