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Solid-state (73) Ge NMR spectroscopy of simple organogermanes

 
 
Affiliation:
Measurement Science and Standards; National Research Council Canada
Language:
English
Type:
Article
Published in:
Chemistry : a European Journal
Date:
2012
Pages :
13770-13779
NRCC #:
NPArC #:
20955687
Keywords:
density functional calculations; germanium; NMR spectroscopy
Abstract:
Germanium-73 is an extremely challenging nucleus to examine by NMR spectroscopy due to its unfavorable NMR properties. Through the use of an ultrahigh (21.1 T) magnetic field, a systematic study of a series of simple organogermanes was carried out. In those cases for which X-ray structural data were available, correlations were drawn between the NMR parameters and structural metrics. These data were combined with DFT calculations to obtain insight into the structures of several compounds with unknown crystal structures.
 
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