Asymptotic energy levels of a rigid asymmetric top

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DOIResolve DOI: http://doi.org/10.1080/00268970701241672
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TypeArticle
Journal titleMolecular Physics
ISSN0026-8976
Volume105
Issue5
Pages679–; # of pages: 1
AbstractThe spectra of larger molecules are often observed to high rotational quantum numbers, and the asymptotic behaviour of the rotational energy levels is of interest. This paper is mainly concerned with the lowest-energy levels for high values of J. These tend to occur in oblate-type doublets, for which E. K. Gora gave an energy-level formula in 1965 that seems to be little known among pure rotational spectroscopists. In particular, the mean energies and splittings of these doublets are discussed and a new derivation of Gora's formula is described.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada; NRC Steacie Institute for Molecular Sciences
Peer reviewedNo
Identifier10107320
NPARC number12328978
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Record identifierb8970bbb-d941-4429-a0fc-e4c264d121b8
Record created2009-09-10
Record modified2016-05-09
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