Resolving multiple non-equivalent metal sites in magnesium-containing metal-organic frameworks by natural abundance 25Mg solid-state NMR spectroscopy

Download
  1. Get@NRC: Resolving multiple non-equivalent metal sites in magnesium-containing metal-organic frameworks by natural abundance 25Mg solid-state NMR spectroscopy (Opens in a new window)
DOIResolve DOI: http://doi.org/10.1002/chem.201300113
AuthorSearch for: ; Search for: ; Search for:
TypeArticle
Journal titleChemistry - A European Journal
ISSN0947-6539
Volume19
Issue14
Pages44324436; # of pages: 5
Subject3QMAS; Local environments; Metal organic framework; Metal sites; Natural abundance; Solid state NMR; Solid-state NMR spectroscopy; Theoretical calculations; Crystalline materials; Magic angle spinning; Microporous materials; Solid state physics; Nuclear magnetic resonance spectroscopy
AbstractIn a spin: Directly differentiating multiple Mg sites in Mg-containing MOFs by 25Mg solid-state NMR spectroscopy is very challenging at natural abundance. By performing 25Mg two-dimensional triple-quantum magic-angle spinning solid-state NMR experiments at a magnetic field of 21.1 T at natural abundance, four non-equivalent Mg sites with very similar local environments in α-Mg3(HCOO)6 were unambiguously resolved (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publication date
LanguageEnglish
AffiliationNational Research Council Canada (NRC-CNRC); Measurement Science and Standards (MSS-SME)
Peer reviewedYes
NPARC number21269790
Export citationExport as RIS
Report a correctionReport a correction
Record identifiere240162e-7471-419c-a4ef-7515f6262725
Record created2013-12-13
Record modified2017-03-23
Bookmark and share
  • Share this page with Facebook (Opens in a new window)
  • Share this page with Twitter (Opens in a new window)
  • Share this page with Google+ (Opens in a new window)
  • Share this page with Delicious (Opens in a new window)